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Lewis acid catalyzed cycloaddition of methylenecyclopropanes with salicylaldehydes.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Jiang, Min Shi, Min |
| Copyright Year | 2010 |
| Abstract | Lewis acid catalyzed cycloaddition of methylenecyclopropanes (MCPs) with o-quinonemethide analogues, derived from the corresponding salicylaldehydes and CH(OEt)(3), produces the corresponding cycloadducts 3 in moderate to high yields at room temperature (20 degrees C). Moreover, the compounds 3 can be transformed to the indene derivatives 5 at high temperature. Plausible mechanisms have been proposed on the basis of control experiments. |
| Starting Page | 44 |
| Ending Page | 61 |
| Page Count | 18 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://s3-eu-west-1.amazonaws.com/pstorage-acs-6854636/4458226/ol100814a_si_003.pdf |
| PubMed reference number | 20462238v1 |
| Alternate Webpage(s) | https://doi.org/10.1021/ol100814a |
| DOI | 10.1021/ol100814a |
| Journal | Organic letters |
| Volume Number | 12 |
| Issue Number | 11 |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Fever Thioctic Acid indene |
| Content Type | Text |
| Resource Type | Article |