NDLI: Copper Mediated Carbometalation Reactions

Content Provider	Semantic Scholar
Author	Mueller, Daniel Marek, Ilan
Copyright Year	2016
Abstract	Since the first discovery of carbocupration of alkynes in the 1970s a tremendous amount of research has been carried out in this field. The exceptionally high selectivities obtained attribute to the great synthetic value of carbocupration reactions. This tutorial review will present the most important features of carbocupration of alkynes and highlight the most relevant reviews. Then a comprehensive review of copper mediated carbometalation of cyclopropenes will follow. The latter method has received much attention over the last decade as it allows the highly selective construction of poly-substituted cyclopropanes which can be transformed into acyclic derivatives bearing one or multiple tertiary or quaternary carbon stereocenters.
File Format	PDF HTM / HTML
DOI	10.1002/chin.201641242
Volume Number	47
Alternate Webpage(s)	https://pubs.rsc.org/en/content/articlepdf/2016/cs/c5cs00897b
Alternate Webpage(s)	https://doi.org/10.1002/chin.201641242
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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