NDLI: Synthesis, Conformational Analysis, and Complexation Study of an Iminosugar-Aza-Crown, a Sweet Chiral Cyclam Analog

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Synthesis, Conformational Analysis, and Complexation Study of an Iminosugar-Aza-Crown, a Sweet Chiral Cyclam Analog

Content Provider	Semantic Scholar
Author	Bordes, Alexandra Poveda, Ana Troadec, Thibault Franconetti, Antonio Ardá, Ana Perrin, Flavie Ménand, Mickaël Sollogoub, Matthieu Guillard, Jérôme Désiré, Jérôme Tripier, Raphäel Jiménez-Barbero, Jesús Blériot, Yves
Copyright Year	2020
Abstract	A new family of chiral C2 symmetric tetraazamacrocycles, coined ISAC for IminoSugar Aza-Crown, incorporating two iminosugars adopting a 4C1 conformation is disclosed. Multinuclear NMR experiments on the corresponding Cd2+ complex show that the ISAC is a strong chelator in water and its tetramine cavity adopts a conformation similar to that of the parent Cd-cyclam complex. Similar behavior is observed with Cu2+ in solution, with enhanced stability compared to the Cu-cyclam complex.
Starting Page	2344
Ending Page	2349
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1021/acs.orglett.0c00503
PubMed reference number	32153195
Journal	Medline
Volume Number	22
Alternate Webpage(s)	http://glyco.labo.univ-poitiers.fr/wp-content/uploads/sites/160/2020/04/OrgLett-ISAC-2020.pdf
Alternate Webpage(s)	https://s3-eu-west-1.amazonaws.com/pstorage-acs-6854636/21956625/ol0c00503_si_001.pdf
Alternate Webpage(s)	https://doi.org/10.1021/acs.orglett.0c00503
Journal	Organic letters
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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