Loading...
Please wait, while we are loading the content...
Olefin metathesis reactions initiated by d2 molybdenum or tungsten complexes
| Content Provider | Semantic Scholar |
|---|---|
| Author | Schrock, Richard R. Lopez, Lourdes Pia H. Hafer, Jillian Singh, Rojendra Sinha, And Amritanshu Müller, Peter |
| Copyright Year | 2005 |
| Abstract | Dimeric or monomeric imido complexes of Mo(IV) or W(IV) will slowly catalyze some olefin metathesis reactions, although it is estimated that <2% of the d2 species is “activated” by the olefin. An ethylene adduct of {W(NAr‘)[OCMe2(CF3)]2}2 can be isolated, which upon heating is transformed into a new dimeric species that contains an ethyl group and a CH activated ortho methyl group in the NAr‘ ligand. |
| Starting Page | 5211 |
| Ending Page | 5213 |
| Page Count | 3 |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/om050583r |
| Volume Number | 24 |
| Alternate Webpage(s) | http://web.mit.edu/pmueller/www/own_papers/schrock_etal_2005.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/om050583r |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
