NDLI: Trithiocarbonates as intrinsic photoredox catalysts and RAFT agents for oxygen tolerant controlled radical polymerization

Content Provider	Semantic Scholar
Author	Fu, Qiang McKenzie, Thomas G. Qiao, Greg Guang Hua
Copyright Year	2017
Abstract	This study reports the discovery that trithiocarbonate RAFT agents can significantly reduce the amount of dissolved oxygen when irradiated with visible light (λmax ≈ 460 nm) in the presence of a sacrificial tertiary amine. By taking advantage of this effect, we conducted a series of photo-CRPs of acrylates without the requirement of pre-degassing the reaction mixtures. In these systems, the trithiocarbonate plays a triple role of photocatalyst for oxygen removal, initiator, and RAFT agent for polymerization control. We believe this robust and facile synthetic method will be beneficial for cost-effective industrial applications as well as the laboratory-scale synthesis of functional polymeric materials.
Starting Page	1519
Ending Page	1526
Page Count	8
File Format	PDF HTM / HTML
DOI	10.1039/C6PY01994C
Alternate Webpage(s)	http://www.rsc.org/suppdata/c6/py/c6py01994c/c6py01994c1.pdf
Alternate Webpage(s)	https://doi.org/10.1039/C6PY01994C
Volume Number	8
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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