NDLI: Metal-free synthesis of methylene-bridged bis-1,3-dicarbonyl compounds via oxidative C–C bond cleavage of tertiary aliphatic amines

Content Provider	Semantic Scholar
Author	Xing, Li-Juan Wang, Xi-Mei Li, Hong-Ying Zhou, Wen Kang, Ning Wang, Peng Wang, Bin
Copyright Year	2014
Abstract	A metal-free Bu4NI mediated oxidative reaction utilizing tertiary aliphatic amines and 1,3-dicarbonyl compounds for the synthesis of methylene-bridged bis-1,3-dicarbonyl compounds has been developed. This reaction involved an unexpected C–C bond cleavage of tertiary aliphatic amines. With this approach, the completely regioselective functionalization of β-carbon on tertiary amines was realized.
Starting Page	26783
Ending Page	26786
Page Count	4
File Format	PDF HTM / HTML
DOI	10.1039/C4RA04419C
Alternate Webpage(s)	https://pubs.rsc.org/en/content/getauthorversionpdf/C4RA04419C
Alternate Webpage(s)	https://doi.org/10.1039/C4RA04419C
Volume Number	4
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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