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A two-dimensional octacyanomolybdate(V)-based ferrimagnet: {[Mn(II)(DMF)4]3[Mo(V)(CN)8]2}n.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Withers, Jeffrey R. Li, Dongfeng Triplet, Jeremy Ruschman, Chad J. Parkin, Sean Wang, Guangbin Yee, Gordon Holmes, Stephen Michael |
| Copyright Year | 2006 |
| Abstract | Treatment of [HNBu3]3[Mo(V)(CN)8] with manganese(II) p-toluenesulfonate in N,N'-dimethylformamide (DMF) affords {[Mn(II)(DMF)4]3[Mo(V)(CN)8]2}n (1) as a two-dimensional network. The structure of 1 consists of [cis-Mn(II)(DMF)4(mu-NC)2]2+ and [trans-Mn(II)(DMF)4(mu-NC)2]2+ units that are linked via cyanides to three-connected [Mo(V)(CN)5(mu-CN)3]3- centers in a 4:2:6 ratio, forming 12-membered rings. Magnetic measurements indicate that 1 is a ferrimagnet (TN = 8 K) that exhibits frequency-dependent behavior in chi". Heating of 1 affords an additional magnetic phase (TN = 21 K) that is absent of linkage isomerism. |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/ic0515251 |
| Alternate Webpage(s) | http://xray.uky.edu/people/parkin/papers/154_ICv45n11p4307.pdf |
| PubMed reference number | 16711670 |
| Alternate Webpage(s) | https://doi.org/10.1021/ic0515251 |
| Journal | Medline |
| Volume Number | 45 |
| Issue Number | 11 |
| Journal | Inorganic chemistry |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |