NDLI: Enantioselective carbene insertion into the N–H bond of benzophenone imine† †Electronic supplementary information (ESI) available. CCDC 1915990 and 1935053. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc03354h

Content Provider	Semantic Scholar
Author	Yang, Jian Ruan, Peiran Yang, Wanlian Feng, Xiaoming Liu, Xiaohua
Copyright Year	2019
Abstract	Efficient enantioselective insertion of α-diazoesters into the N-H bond of N-sp2-hybridized benzophenone imine was realized by using Rh2(esp)2 and chiral guanidine cooperative catalysis. Both aliphatic and aromatic substituted α-amino esters were obtained in high yields (up to 99%) and good enantioselectivities (up to 95.5 : 4.5 er) under mild reaction conditions.
Starting Page	10305
Ending Page	10309
Page Count	5
File Format	PDF HTM / HTML
DOI	10.1039/c9sc03354h
PubMed reference number	32110317
Journal	Medline
Volume Number	10
Alternate Webpage(s)	http://www.rsc.org/suppdata/c9/sc/c9sc03354h/c9sc03354h1.pdf
Alternate Webpage(s)	https://pubs.rsc.org/en/content/articlepdf/2019/sc/c9sc03354h
Alternate Webpage(s)	https://doi.org/10.1039/c9sc03354h
Journal	Chemical science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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