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Controlled interparticle spacing through self-assembly of Au nanoparticles and poly(amidoamine) dendrimers.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Frankamp, Benjamin L. Boal, Andrew K. Rotello, Vincent M. |
| Copyright Year | 2002 |
| Abstract | Control of particle-particle spacing is a key determinant of optical, electronic, and magnetic properties of nanocomposite materials. We have used poly(amidoamine) (PAMAM) dendrimers to assemble carboxylic acid-functionalized mixed monolayer protected clusters (MMPCs) through acid/base chemistry between the particle and dendrimer. Small angle X-ray scattering was then used to establish average inter-MMPC distances. Five generations of PAMAM dendrimer (0, 1, 2, 4, 6) were investigated, with a monotonic increase in interparticle spacing from 4.1 to 6.1 nm observed with increasing generation. |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/ja0280426 |
| PubMed reference number | 12487569 |
| Journal | Medline |
| Volume Number | 124 |
| Issue Number | 51 |
| Alternate Webpage(s) | http://www.colorado.edu/physics/phys7450/phys7450_sp05/colloids/soft%20colloids/frankamp_2002.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/ja0280426 |
| Journal | Journal of the American Chemical Society |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |