NDLI: Cyano-borrowing reaction: nickel-catalyzed direct conversion of cyanohydrins and aldehydes/ketones to β-cyano ketone† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc00640k

Content Provider	Semantic Scholar
Author	Li, Zhao-Feng Li, Qian Ren, Li-Qing Li, Qing-Hua Peng, Yungui Liu, Tang-Lin
Copyright Year	2019
Abstract	A direct nickel-catalyzed, high atom- and step-economical reaction of cyanohydrins with aldehydes or ketones via an unprecedented "cyano-borrowing reaction" has been developed. Cleavage of the C-CN bond of cyanohydrins followed by aldol condensation and conjugate addition of cyanide to α,β-unsaturated ketones proceeded to deliver a range of racemic β-cyano ketones with good to high yields. The practical procedure with the use of a commercial and less-toxic CN source bodes well for wide application of this protocol.
Starting Page	5787
Ending Page	5792
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1039/C9SC00640K
Alternate Webpage(s)	http://www.rsc.org/suppdata/c9/sc/c9sc00640k/c9sc00640k1.pdf
PubMed reference number	31293766
Alternate Webpage(s)	https://doi.org/10.1039/C9SC00640K
Journal	Medline
Volume Number	10
Journal	Chemical science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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