Cyanido-bridged heterometallic oligonuclear complexes and coordination polymers constructed using tridentate schiff-base ligands: Synthesis, crystal structures, and magnetic and luminescence properties. A new trimeric water cluster

Content Provider	Semantic Scholar
Author	Maxim, Catalin Tuna, Floriana Madalan, Augustin M. Avarvari, Narcis Andruh, Marius
Copyright Year	2012
Abstract	Five new CuII–AgI, CuII–CuI, and ZnII–AuI complexes have been obtained starting from copper(II) and, respectively, zinc(II) complexes with (NNO) Schiff-base ligands: [{(H2O)(saldmen)Cu}{(NC)Ag(CN)}] 1, 1∞[{Cu2(salaepipH)2(μ-CN)}{μ-[Ag(CN)2]}](ClO4)2·4H2O 2, 1∞[{(salaepy)Cu}{μ-[Ag(CN)2]}] 3, 1∞[{(salaepy)Cu}{μ-[Cu(CN)2]}] 4, [(salaepy)Zn-NCAuCN]2·H2O 5. The Schiff-base ligands (Hsaldmen, Hsalaepip, Hsalaepy) have been obtained by reacting the salicylaldehyde with N,N-dimethyletylenediamine, N-(2-aminoethyl)piperazine, and, respectively, 2-(2-aminoethyl)-pyridine. The structures of compounds 1 and 5 consist of discrete bi- and, respectively, tetranuclear species. The analysis of the packing diagram for crystal 1 reveals the formation of supramolecular double chains sustained by hydrogen-bond interactions involving the aqua ligand. Compounds 2, 3, and 4 are one-dimensional coordination polymers. The structure of 2 consists of chains constructed from {Cu(salaepip)} nodes bridged alternatively by [Ag(CN)2]− an...
Starting Page	1654
Ending Page	1665
Page Count	12
File Format	PDF HTM / HTML
DOI	10.1021/cg2016947
Alternate Webpage(s)	http://www.unibuc.ro/n/organizare/dirresumane/post-vaca/desf-conc-orga-in-facu/docs/2016/ian/13_12_17_58cv_catalin_maxim_rom.pdf
Alternate Webpage(s)	https://doi.org/10.1021/cg2016947
Volume Number	12
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article