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UV photoelectron spectroscopy and outer valence electronic structure of dihalobenzenes
| Content Provider | Semantic Scholar |
|---|---|
| Author | Novak, Igor Klasinc, L. Šket, Boris Chong, Delano P. McGlynn, Sean P. |
| Copyright Year | 2014 |
| Abstract | The electronic structures of nine dihalobenzenes (C6H4FX; X = Cl, Br, I) have been studied by UV photoelectron spectroscopy (UPS) and assigned by comparison with the reported spectra of monoha-lobenzenes (C6H5X; X = Cl, Br, I). and quantum chemical calculations. Our results show that the fluorine substituent modifies energies of π- and halogen lone pair orbitals to a significant degree depending on its location (topology). We also demonstrate that the inductive effect of fluorine atom on the benzene ring can be readily observed and interpreted. |
| Starting Page | 495 |
| Ending Page | 499 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| DOI | 10.5562/cca2438 |
| Volume Number | 87 |
| Alternate Webpage(s) | https://researchoutput.csu.edu.au/ws/portalfiles/portal/11552862/73225_1000002150postpub.pdf |
| Alternate Webpage(s) | http://hrcak.srce.hr/file/194363 |
| Alternate Webpage(s) | https://doi.org/10.5562/cca2438 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
