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Eco-friendly synthesis of pyridines via rhodium-catalyzed cyclization of diynes with oximes
| Content Provider | Semantic Scholar |
|---|---|
| Author | Xu, Fen Lian Wang, Chunxiang Wang, Haolong Li, Xincheng Wan, Boshun |
| Copyright Year | 2015 |
| Abstract | We describe a new route for the synthesis of pyridines via [2 + 2 + 2] cycloaddition of diynes and oximes catalyzed by Rh(NBD)2BF4/MeO-Biphep using ethanol as an alternative green reaction medium, affording the desired pyridine derivatives in yields of up to 93%. This environmentally friendly method meets the requirement for green chemistry by minimizing pollution from solvents and is tolerant of a range of functional groups. |
| Starting Page | 799 |
| Ending Page | 803 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C4GC01756K |
| Volume Number | 17 |
| Alternate Webpage(s) | http://www.chs.dicp.ac.cn/download/2015-05.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C4GC01756K |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |