NDLI: Photoelectron-photofragment coincidence study of OHF-: transition state dynamics of the reaction OH + F --> O + HF.

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Photoelectron-photofragment coincidence study of OHF-: transition state dynamics of the reaction OH + F --> O + HF.

Content Provider	Semantic Scholar
Author	Deyerl, Hans-Jürgen Continetti, Robert E.
Copyright Year	2005
Abstract	A photoelectron-photofragment coincidence (PPC) study of the dissociative photodetachment of OHF at a photon energy of 4.80 eV is presented. The correlated electron kinetic energy (eKE) and translational energy release (E(T)) into the O + HF + e- products yield information on the potential energy surface close to the transition state of the neutral reaction OH + F --> O + HF. The correlation spectrum shows two different features in the energetically allowed O + HF product channel: (a) diagonal ridges, resulting from direct dissociative photodetachment (DPD) and (b) areas with higher E(T) in the neutral fragments from nonadiabatic dissociation. The total translational energy spectrum (E(TOT) = eKE + ET) reveals a vibrationally resolved product state distribution. These results are discussed in the context of recent theoretical studies of the dissociative photodetachment of OHF-.
File Format	PDF HTM / HTML
DOI	10.1039/B414604B
PubMed reference number	19791372
Journal	Medline
Volume Number	7
Issue Number	5
Alternate Webpage(s)	http://checont6.ucsd.edu/pdf/064.deyerl.2005.pdf
Alternate Webpage(s)	https://doi.org/10.1039/B414604B
Journal	Physical chemistry chemical physics : PCCP
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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