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Palladium nanoparticle catalysis: borylation of aryl and benzyl halides and one-pot biaryl synthesis via sequential borylation-Suzuki–Miyaura coupling
| Content Provider | Semantic Scholar |
|---|---|
| Author | Bej, Ansuman Srimani, Dipankar Sarkar, Amitabha |
| Copyright Year | 2012 |
| Abstract | Palladium nanoparticles generated in PEG catalyze the reaction of bis(pinacolato)diboron with various aryl/benzyl halides to afford aryl/benzyl boronates in high yield. Arylboronates thus prepared, have been directly used in the Suzuki–Miyaura coupling reaction with different aryl halides and benzyl halides in a convenient one-pot, two-step solvent free green synthesis of unsymmetrical biaryls and diarylmethanes. |
| Starting Page | 661 |
| Ending Page | 667 |
| Page Count | 7 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C2GC16111G |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/gc/c2/c2gc16111g/c2gc16111g.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C2GC16111G |
| Volume Number | 14 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |