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Bis{3-amino-1-carbamothioyl-5-[(2-{[(5-methyl-1H-imidazol-3-ium-4-yl)methyl]sulfanyl}ethyl)amino]-1H-1,2,4-triazol-4-ium} hexachloridobismuthate(III) nitrate dihydrate
| Content Provider | Semantic Scholar |
|---|---|
| Author | Hossain, G. M. Golzar |
| Copyright Year | 2013 |
| Abstract | The asymmetric unit of the title hydrated salt, (C10H18N8S2)2[BiCl6]NO3·2H2O, contains two independent 3-amino-1-carbamo-thioyl-5-[(2-{[(5-methyl-1H-imidazol-3-ium-4-yl)meth-yl]sulfan-yl}eth-yl)amino]-1H-1,2,4-triazol-4-ium cations, one hexa-chloridobismuthate anion, one nitrate anion and two solvent water mol-ecules. The dihedral angles between the imidazole and triazole rings in the cations are 44.7 (3) and 89.4 (3)°. The Bi(III) ion is coordinated by six chloride ligands in a slightly distorted octa-hedral geometry. In each cation, an intra-molecular N-H⋯S hydrogen bond is observed. In the crystal, N-H⋯Cl, N-H⋯S, N-H⋯O, O-H⋯Cl, O-H⋯S and O-H⋯O hydrogen bonds connect the components into a three-dimensional network. In addtion, π-π stacking inter-actions between inversion-related triazole rings are observed, with a centroid-centroid distance of 3.322 (3) Å |
| Starting Page | m402 |
| Ending Page | m403 |
| Page Count | 2 |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S1600536813016449 |
| PubMed reference number | 24046574 |
| Journal | Medline |
| Volume Number | 69 |
| Alternate Webpage(s) | http://journals.iucr.org/e/issues/2013/07/00/lh5614/lh5614.pdf |
| Alternate Webpage(s) | http://ftp.ncbi.nlm.nih.gov/pub/pmc/49/08/e-69-0m402.PMC3772431.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536813016449 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
