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N Synthesis of Highly Soluble Fluoro Containing Metal-phthalocyanines and ( Hexafluoroisopropylidene )-bridged Metal-phthalocyanine Polymers
| Content Provider | Semantic Scholar |
|---|---|
| Author | Darwish, Wael M. El-Ghaffar, Mahmoud A. Abd |
| Copyright Year | 2013 |
| Abstract | OVEL soluble peripherally tetrasubstituted metal-phthalocyanines: 2(3),9 10), ......16 (17),23(24) – tetrakis 2'-(4-hexafluoroisopropylidene-phthalic acid)-phthalocyanines [(R4Pc)M] where R= (4,4 -̀(hexafluoroisopropylidene) bis-phthalic acid and M= Co(II), Ni(II) and Cu(II) 2-4, have been prepared. Additionally, the soluble hexafluoroisopropylidene bridged high molecular weight phthalocyanines 5-7 were obtained by controlling the reaction conditions such as molar ratio of the reactant, reaction time and temperature. Structural and spectral investigations (FAB-MS, MALDI-TOF-MS, H-NMR, atomic absorption spectroscopy (AAS), elemental analysis, UV/Vis, FTIR, TGA, and GPC) of the prepared phthalocyanines revealed some interesting observations. |
| File Format | PDF HTM / HTML |
| DOI | 10.21608/ejchem.2010.1272 |
| Alternate Webpage(s) | http://www.ejchem.journals.ekb.eg/article_1272_05e43b8f3ff2834fdef7ad2f33c5e0a5.pdf |
| Alternate Webpage(s) | https://doi.org/10.21608/ejchem.2010.1272 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |