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Excimer and exciplex formation in a pair of bright phosphorescent isomers constructed from Cu3(pyrazolate)3 and Cu3I3 coordination luminophores
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zhan, Shun-Ze Li, Mian Zhou, Xiao-Ping Ng, Seik Weng |
| Copyright Year | 2011 |
| Abstract | Reported herein are a pair of supramolecular pseudo-isomers, namely, (Cu3I3)(Cu3L3)2·H2O (1) and (Cu3I3)(Cu3L3)2 (2) (L = 3-(4-pyridyl)-5-isobutyl-pyrazolate), both of which incorporate Cu3Pz3 (Pz = pyrazolate) and Cu3I3 clusters as luminophores. The two complexes show distinct yellow (570 nm) and orange (638 nm) emissions, which are ascribed to the formation of the excimer and exciplex involving the same or different copper(I)-cluster-based luminophores. |
| Starting Page | 1457 |
| Ending Page | 1459 |
| Page Count | 3 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C1RA00566A |
| Volume Number | 1 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/ra/c1/c1ra00566a/c1ra00566a.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C1RA00566A |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
