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High-Precision Measurements of the 143Nd/144Nd Isotope Ratio in Certified Reference Materials without Nd and Sm Separation by Multiple Collector Inductively Coupled Plasma Mass Spectrometry
| Content Provider | Semantic Scholar |
|---|---|
| Author | Yang, Yuguang Wu, Fu-Yuan Xie, Lie-Wen Zhang, Yanbin |
| Copyright Year | 2009 |
| Abstract | We present a precise and accurate method for the determination of 143Nd/144Nd isotope ratio without Nd and Sm separation by multiple collector inductively coupled plasma mass spectrometry. We corrected instrumental mass discrimination by applying the natural constant 146Nd/144Nd ratio as an internal standard after isobaric interference correction of 144Sm on 144Nd using interference-free 147Sm/149Sm ratio for Sm mass fractionation. The present method was validated by duplicate analyses of several certified reference materials after dissolution and cation-exchange resin purification. The precision (2σ) of the 143Nd/144Nd ratio is less than 10 ppm (internal) and 20 ppm (external), respectively. |
| Starting Page | 142 |
| Ending Page | 150 |
| Page Count | 9 |
| File Format | PDF HTM / HTML |
| DOI | 10.1080/00032710903276539 |
| Volume Number | 43 |
| Alternate Webpage(s) | http://www.igg.cas.cn/xwzx/yjcg/201004/W020100406336883103827.pdf |
| Alternate Webpage(s) | https://doi.org/10.1080/00032710903276539 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |