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The Electric Field Gradient of 111 Ag in Macrocyclic Crown
| Content Provider | Semantic Scholar |
|---|---|
| Author | Thioethers Heinrich, Frank Ctortecka, Bernd Troeger, Wolfgang |
| Abstract | Time differential perturbed angular correlation experiments and ab-initio density functional theory calculation were used to determine the electric field gradients of the metal centres of the macrocyclic crown thioethers Ag(15S5)[BF4], Ag(18S6-CH2OH)[CF3SO3], Ag(18S6) , Ag(19S6-OH)[Tosylat] and Ag(20S6-OH)[CF3SO3]. The density functional theory calculations have been performed with the Amsterdam Density Functional code ADF. A Bfingerprint system^ is introduced, which allows to assign electric field gradients to certain Ag coordinations in these crown thioether complexes. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://page-one.springer.com/pdf/preview/10.1007/3-540-30924-1_13 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
