NDLI: Rotationally resolved photoionization dynamics of hot CO fragmented from OCS

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Rotationally resolved photoionization dynamics of hot CO fragmented from OCS

Content Provider	Semantic Scholar
Author	Rijs, Anouk M. Backus, Ellen H. G. Wang, Kwanghsi McKoy, Vincent
Copyright Year	2002
Abstract	The photoionization dynamics of rotationally hot CO, photodissociated from OCS, have been studied using laser photoelectron spectroscopy via the intermediate B S Rydberg state leading to the X S of the ion. The photodissociation of OCS near 230 nm produces rotationally hot, but vibrationally cold CO (X S,N9,v950,1) fragments along withS (D) atoms. These high rotational levels show photoelectron spectra with a very strong DN50 transition and weaker DN 561, 62, and63 transitions. Agreement between measured and calculated spectra is good and suggests that there is significant angular momentum coupling in the photoelectron orbital. In the ionization step not onlyDv50, but also off-diagonal, non-Franck–Condon ( DvÞ0) transitions are observed. The intensities of these transitions vary strongly within the region studied and can be explained by the excitation of superexcited Rydberg states with an A P core. © 2002 American Institute of Physics.@DOI: 10.1063/1.1434993 #
File Format	PDF HTM / HTML
Alternate Webpage(s)	https://research.vu.nl/ws/portalfiles/portal/2603093/233492.pdf
Alternate Webpage(s)	http://authors.library.caltech.edu/61602/1/1.1434993.pdf
Language	English
Access Restriction	Open
Subject Keyword	2-picoline AngularJS Coherent Excitation Image resolution Initial Volume of Distribution Ions Molecular orbital Original Chip Set Photoelectric effect Photoelectrochemical process Photoelectron Spectroscopy
Content Type	Text
Resource Type	Article

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