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Syntheses , Crystal Structures , and Properties of Three Two-Dimensional Complexes Constructed by Flexible ( 2 , 3-Pyridylmethyl ) amine 1
| Content Provider | Semantic Scholar |
|---|---|
| Author | Yue, Clarence Meng Yi. Gao, Dong Zhao Wang, Xiangshe |
| Abstract | Three two-dimensional coordination polymers [Cd(2,3-Pyma)Cl2]n (I), {[Cd(2,3-Pyma)(1,4Chdc)] · 4H2O}n (II) and {[Zn2(2,3-Pyma)(1,2,4,5-Bttc)(H2O)4] · 6H2O}n (III) (2,3-Pyma = (2,3-pyridylmethyl)amine, H2-1,4-Chdc = 1,4-cyclohexanedicarboxylic acid, and H4-1,2,4,5-Bttc = 1,2,4,5-benzenetetracarboxylic acid) have been synthesized and structurally characterized by single crystal X-ray crystallography (CIF files CCDC nos. 989461 (I), 1055685 (II) and 1055686 (III)). Three complexes are all twodimensional layer networks bridged by the f lexible 2,3-Pyma ligands or the carboxylate ligands. It is noted that the f lexible 1,4-Chdc ligands bind the Cd2+ ions into a helical chain structure in complex II. The photoluminescence and thermal properties are investigated. DOI: 10.1134/S107032841602010X |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://page-one.springer.com/pdf/preview/10.1134/S107032841602010X |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
