Jet-Cooled Laser-Induced Fluorescence Spectroscopy of Some Alkoxy Radicals

Content Provider	Semantic Scholar
Author	Carter, Christopher C. Atwell, Jeffrey R. Gopalakrishnan, And Sandhya Miller, Terry A.
Copyright Year	2000
Abstract	The laser-induced fluorescence spectra of jet-cooled alkoxy radicals were recorded. Spectra were observed for both isomers of propoxy and all three isomers of butoxy. In nearly all cases, the vibrational structure of the spectra are dominated by a C−O stretch progression, which, however, terminates much more abruptly for the primary isomers than for the more branched ones. For each of the radicals (except t-butoxy), a number of low-frequency (below the C−O stretch) vibrational modes were assigned by analogies among the alkoxy spectra and reference to frequencies from ab initio calculations. A few higher frequency modes were also assigned using similar approaches.
Starting Page	9165
Ending Page	9170
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1021/jp001835z
Volume Number	104
Alternate Webpage(s)	https://molspect.chemistry.ohio-state.edu/goes/papers/pub283.pdf
Alternate Webpage(s)	https://doi.org/10.1021/jp001835z
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article