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Palladium-Catalyzed Allylation/Benzylation of H-Phosphinate Esters with Alcohols
| Content Provider | Semantic Scholar |
|---|---|
| Author | Fers-Lidou, Anthony Berger, Olivier Montchamp, J. L. |
| Copyright Year | 2016 |
| Abstract | The Pd-catalyzed direct alkylation of H-phosphinic acids and hypophosphorous acid with allylic/benzylic alcohols has been described previously. Here, the extension of this methodology to H-phosphinate esters is presented. The new reaction appears general, although its scope is narrower than with the acids, and its mechanism is likely different. Various alcohols are examined in their reaction with phosphinylidene compounds R¹R²P(O)H. |
| Starting Page | 106 |
| Ending Page | 120 |
| Page Count | 15 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://res.mdpi.com/molecules/molecules-21-01295/article_deploy/molecules-21-01295-s001.pdf?attachment=1&filename= |
| Alternate Webpage(s) | http://summit.sfu.ca/system/files/iritems1/17339/publication_molecules_montchamp.pdf |
| PubMed reference number | 27689979v1 |
| Volume Number | 21 |
| Journal | Molecules |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Alkylation Carnitine esters/Creatinine:MRto:Pt:Urine:Qn Carnitine esters/Creatinine:SRto:Pt:Urine:Qn Cholesterol Esters Esterification Fluorinated Telomer Alcohols Hypophosphorus Acid Palladium Parkinson Disease Phosphinic Acids Thioctic Acid |
| Content Type | Text |
| Resource Type | Article |