NDLI: First example of the ribbed-functionalized iron(ii) clathrochelate with six pendante closo-borate substituents

Content Provider	Semantic Scholar
Author	Kuznetsov, N. T. Makarenko, I. G. Belaya Dolganov, Alexander V. Zelinskii, Genrikh E. Matveev, E. Yu. Zhizhin, Konstantin Yu. Voloshin, Ya. Z. Bubnov, Yu. N.
Copyright Year	2011
Abstract	The nucleophilic substitution of the reactive chlorine atoms of the n-butylboron-capped hexachlorine-containing clathrochelate precursor with the thiol-terminated closo-decaborate (PPh4)2[B10H9OCH2CH2OCH2CH2SH] in the presence of triethylamine afforded the closo-decaborate-containing clathrochelate dodecaanion [Fe{[(B10H9OCH2CH2OCH2CH2S)2Gm]3-(BBun)2}]12−, which was isolated in the form of its tetraphenylphosphonium and sodium salts. The complexes obtained were characterized using elemental analysis, UV-VIS, 1H, 11B, and 13C{1H} NMR, and IR spectroscopies.
Starting Page	2518
Ending Page	2521
Page Count	4
File Format	PDF HTM / HTML
DOI	10.1007/s11172-011-0387-1
Volume Number	60
Alternate Webpage(s)	https://page-one.springer.com/pdf/preview/10.1007/s11172-011-0387-1
Alternate Webpage(s)	https://doi.org/10.1007/s11172-011-0387-1
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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