NDLI: Rapid access to diverse, trifluoromethyl-substituted alkenes using complementary strategies† †Electronic supplementary information (ESI) available. CCDC 1811877, 1817386–1817390. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc05420c

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Rapid access to diverse, trifluoromethyl-substituted alkenes using complementary strategies† †Electronic supplementary information (ESI) available. CCDC 1811877, 1817386–1817390. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc05420c

Content Provider	Semantic Scholar
Author	Phelan, James P. Wiles, Rebecca J. Lang, Simon B. Kelly, Christopher B. Molander, Gary A.
Copyright Year	2018
Abstract	Two synergistic approaches to the facile assembly of complex α-trifluoromethyl alkenes are described. Using α-trifluoromethyl-β-silyl alcohols as masked trifluoromethyl alkenes, cross-coupling or related functionalization processes at distal electrophilic sites can be executed without inducing Peterson elimination. Subsequent Lewis acidic activation affords functionalized α-trifluoromethyl alkenes. Likewise, the development of a novel α-trifluoromethylvinyl trifluoroborate reagent complements this approach and allows a one-step cross-coupling of (hetero)aryl halides to access a broad array of complex α-trifluoromethyl alkenes.
Starting Page	3215
Ending Page	3220
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1039/c7sc05420c
PubMed reference number	29732105
Journal	Medline
Volume Number	9
Alternate Webpage(s)	http://www.rsc.org/suppdata/c7/sc/c7sc05420c/c7sc05420c1.pdf
Alternate Webpage(s)	https://ftp.ncbi.nlm.nih.gov/pub/pmc/oa_pdf/29/c0/SC-009-C7SC05420C.PMC5916225.pdf
Alternate Webpage(s)	http://pubs.rsc.org/en/content/articlepdf/2018/sc/c7sc05420c
Alternate Webpage(s)	https://doi.org/10.1039/c7sc05420c
Journal	Chemical science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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