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Hydrothermal modification of the alumina catalyst for the skeletal isomerization of n-butenes
| Content Provider | Semantic Scholar |
|---|---|
| Author | Mukhambetov, Ildar N. Egorova, Svetlana R. Mukhamed’yarova, Aliya N. Lamberov, Aleksandr |
| Copyright Year | 2018 |
| Abstract | Abstract Hydrothermal modification of the alumina catalyst of n-butenes skeletal isomerization was investigated. It is shown that during the hydrothermal treatment of γ-Al2O3 and subsequent calcination its activity in skeletal isomerization of n-butenes first increases, and then it decreases with a rise of the hydrothermal treatment duration. This behavior is due to a similar change in the content of the strong Lewis acid sites of alumina, which are the active centers of reaction and they can be identified by IR-spectroscopy of the adsorbed pyridine and EPR-spectroscopy of the adsorbed anthraquinone. We report the mechanism of new Lewis acid sites formation at the γ-Al2O3 hydrothermal treatment containing X-ray amorphous component. |
| Starting Page | 64 |
| Ending Page | 70 |
| Page Count | 7 |
| File Format | PDF HTM / HTML |
| DOI | 10.1016/j.apcata.2018.01.024 |
| Alternate Webpage(s) | https://shelly.kpfu.ru/e-ksu/docs/F350383774/1_s2.0_S0926860X18300413_main.pdf |
| Alternate Webpage(s) | https://doi.org/10.1016/j.apcata.2018.01.024 |
| Volume Number | 554 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |