Loading...
Please wait, while we are loading the content...
Similar Documents
Alkynes and Azides: Not Just for Click Reactions.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Hyatt, I. F. Dempsey Meza-Aviña, Maria Elena Croatt, Mitchell P. |
| Copyright Year | 2012 |
| Abstract | We recently reported two unexplored reactivities of alkynes and azides. The first method reacts nucleophilic alkynes and electrophilic azides to synthesize sulfonyl-substituted 1,5-disubstituted 1,2,3-triazoles. The second method reacts electrophilic alkynes with nucleophilic azides to form alkynyl azides that immediately extrude dinitrogen to form cyanocarbenes which were trapped by O–H insertion, sulfoxide complexation, and cyclopropanation. The design and discovery of these reactions, along with key observations, is discussed herein. |
| File Format | PDF HTM / HTML |
| DOI | 10.1055/s-0032-1317545 |
| Alternate Webpage(s) | http://libres.uncg.edu/ir/uncg/f/M_Croatt_Alkynes_2012.pdf |
| Alternate Webpage(s) | https://doi.org/10.1055/s-0032-1317545 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |