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Precision polymers: a kinetic approach for functional poly(norbornenes)
| Content Provider | Semantic Scholar |
|---|---|
| Author | Moatsou, Dafni Hansell, Claire F. Reilly, Rachel K. O’ |
| Copyright Year | 2014 |
| Abstract | The potential control over monomer sequence in the ring-opening metathesis polymerization of functional norbornenes is explored based on the difference in reactivity of endo and exo isomers. This kinetic approach allows the rapid consumption of the exo-norbornene and insertion onto the growing poly(norbornene) chain within a narrow region of the overall polymer chain, whilst maintaining a homogeneous backbone. We herein demonstrate that this can be achieved using a range of functional monomers easily derived from commercially available precursors while their polymerization is carried out in a controlled manner. |
| Starting Page | 2246 |
| Ending Page | 2250 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C4SC00752B |
| Volume Number | 5 |
| Alternate Webpage(s) | http://wrap.warwick.ac.uk/78269/1/WRAP_c4sc00752b.pdf |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/getauthorversionpdf/C4SC00752B |
| Alternate Webpage(s) | https://doi.org/10.1039/C4SC00752B |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
