NDLI: Microporous covalent triazine polymers: efficient Friedel–Crafts synthesis and adsorption/storage of CO2 and CH4

Content Provider	Semantic Scholar
Author	Puthiaraj, Pillaiyar Cho, Sung-Min Ahn, Wha-Seung
Copyright Year	2015
Abstract	Two kinds of microporous covalent triazine-based organic polymers (MCTPs) were synthesized from inexpensive starting materials via a simple and cost effective Friedel–Crafts reaction route, and their CO2 and CH4 gas uptake capacities were investigated. The synthesized microporous materials showed high BET surface areas of 1452 (MCTP-1) and 859 m2 g−1 (MCTP-2). MCTP-1 exhibited a significant CO2 uptake capacity (204.3 mg g−1, 273 K/1 bar) with moderate CO2/N2 selectivity (15.4), whereas MCTP-2 showed a moderate CO2 uptake capacity (160.6 mg g−1, 273 K/1 bar) but exceptional CO2/N2 selectivity (68.6). MCTP-1 also exhibited substantial CO2 (497.4 mg g−1) and CH4 (85.4 mg g−1) storage capacities at 300 K and 35 bar.
Starting Page	6792
Ending Page	6797
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1039/C5TA00665A
Alternate Webpage(s)	https://pubs.rsc.org/en/content/getauthorversionpdf/C5TA00665A
Alternate Webpage(s)	http://www.rsc.org/suppdata/c5/ta/c5ta00665a/c5ta00665a1.pdf
Alternate Webpage(s)	https://doi.org/10.1039/C5TA00665A
Volume Number	3
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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