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Synthetic transformations of sesquiterpene lactones 6. Alantolactone and isoalantolactone derivatives in the Heck reaction
| Content Provider | Semantic Scholar |
|---|---|
| Author | Shults, Elvira E. Belovodskii, A. V. Shakirov, Makhmut M. Tolstikov, Genrikh A. |
| Copyright Year | 2012 |
| Abstract | The Heck reaction of the eudesman-type methylidenelactones (alantolactone, alloalantolactone, and 4,15-epoxyisoalantolactone) with haloarenes afforded the corresponding (E)-13-aryleudesma-4(15),11(13)-dien-8β,12-olides and 11-arylmethyl-13-noreudesma-4(15),7(11)-dien-8α,12-olides. The yields and the ratios of the arylation products depended on the reaction conditions and the structure of lactone. Certain side processes were found to take place. |
| Starting Page | 1975 |
| Ending Page | 1985 |
| Page Count | 11 |
| File Format | PDF HTM / HTML |
| DOI | 10.1007/s11172-012-0274-4 |
| Volume Number | 61 |
| Alternate Webpage(s) | https://page-one.springer.com/pdf/preview/10.1007/s11172-012-0274-4 |
| Alternate Webpage(s) | https://doi.org/10.1007/s11172-012-0274-4 |
| Journal | Russian Chemical Bulletin |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |