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trans-1,2-Disiloxybenzocyclobutene, an adequate partner for the auto-oxidation: EPR/spin trapping and theoretical studies.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Drujon, J. Rahmani, Raphaël Héran, Virginie Blanc, Romain Carissan, Yannick Olivier Tuccio, Béatrice N. Commeiras, Laurent Parrain, Jean-Luc |
| Copyright Year | 2014 |
| Abstract | The auto-oxidation of trans-1,2-disiloxybenzocyclobutene was found to be very efficient, giving endo-peroxide in quantitative yield. Each step of the mechanism of spin-forbidden addition of triplet oxygen O2((3)Σg) was studied by both EPR/spin trapping and theoretical studies. |
| Starting Page | 142 |
| Ending Page | 146 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/cp/c3/c3cp55077j/c3cp55077j1.pdf |
| PubMed reference number | 24626812v1 |
| Alternate Webpage(s) | https://doi.org/10.1039/c3cp55077j |
| DOI | 10.1039/c3cp55077j |
| Journal | Physical chemistry chemical physics : PCCP |
| Volume Number | 16 |
| Issue Number | 16 |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | MANEA gene Oxygen 100 % Gas for Inhalation Peroxides Spin Trapping oxidation |
| Content Type | Text |
| Resource Type | Article |