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Ligand-controlled palladium-catalyzed regiodivergent Suzuki-Miyaura cross-coupling of allylboronates and aryl halides.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Yang, Yang Buchwald, Stephen L. |
| Copyright Year | 2013 |
| Abstract | An orthogonal set of catalyst systems has been developed for the Suzuki-Miyaura coupling of 3,3-disubstituted and 3-monosubstituted allylboronates with (hetero)aryl halides. These methods allow for the highly selective preparation of either the α- or the γ-isomeric coupling product. |
| File Format | PDF HTM / HTML |
| PubMed reference number | 23837686 |
| Journal | Medline |
| Volume Number | 135 |
| Issue Number | 29 |
| Alternate Webpage(s) | http://dspace.mit.edu/openaccess-disseminate/1721.1/93917 |
| Alternate Webpage(s) | https://dspace.mit.edu/bitstream/handle/1721.1/93917/Buchwald_Ligand-controlled.pdf?isAllowed=y&sequence=1 |
| Alternate Webpage(s) | https://doi.org/10.1021/ja405950c |
| Journal | Journal of the American Chemical Society |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |