NDLI: Hydroformylation of Cyclohexene with Carbon Dioxide and Hydrogen Using Ruthenium Carbonyl Catalyst: Influence of Pressures of Gaseous Components

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Hydroformylation of Cyclohexene with Carbon Dioxide and Hydrogen Using Ruthenium Carbonyl Catalyst: Influence of Pressures of Gaseous Components

Content Provider	Semantic Scholar
Author	Fujita, Shin-Ichiro Okamura, Shuhei Akiyama, Yoshinari Arai, Masahiko
Copyright Year	2007
Abstract	Hydroformylation of cyclohexene was studied with a c talyst system of Ru3(CO)12 and LiCl using H2 and CO2 instead of CO in NMP. The influence of H 2 and CO2 pressures on the total conversion and the product istribution was examined. It was shown that increasing total pressure of H 2 and CO2 promoted the reverse water gas shift reaction and increased the yield of cyclohexanecarb oxaldehyde. Its hydrogenation to cyclohexanemethanol was promoted with increasing H 2 pressure but suppressed with increasing CO2 pressure. Cyclohexane was also formed along with t hose products and this direct hydrogenation was suppressed with increasing CO2 pressure. The roles of CO 2 as a promoter as well as a reactant were further examine d by phase behavior observations and high pressure FTIR measurements.
Starting Page	749
Ending Page	759
Page Count	11
File Format	PDF HTM / HTML
Alternate Webpage(s)	http://ftp.ncbi.nlm.nih.gov/pub/pmc/94/cd/ijms-08-00749.PMC3715799.pdf
Alternate Webpage(s)	http://www.mdpi.com/1422-0067/8/8/749/pdf
Alternate Webpage(s)	http://www.mdpi.org/ijms/papers/i8080749.pdf
Alternate Webpage(s)	http://www.mdpi.com/1422-0067/8/8/749/pdf/
PubMed reference number	3715799
Volume Number	8
Language	English
Access Restriction	Open
Subject Keyword	Behavior Observation Techniques Carbon Dioxide Carbonyl Cyanide p-Trifluoromethoxyphenylhydrazone Cyclohexanes Deuterium H2 Database Engine Hydrogen Hydrogenation Lithium Chloride Mod (video gaming) Spectroscopy, Fourier Transform Infrared cyclohexene cyclohexylmethanol
Content Type	Text
Resource Type	Article

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