Dynamic behaviour of monohaptoallylpalladium species: internal coordination as a driving force in allylic alkylation chemistry† †Electronic supplementary information (ESI) available: Experimental procedures, X-ray crystallographic data, characterization data, chiral chromatographic analyses, and com

Content Provider	Semantic Scholar
Author	Xie, Lan-Gui Bagutski, Viktor Audisio, Davide Wolf, Larry M. Schmidts, Volker Hofmann, Kathrin Wirtz, Cornelia Thiel, Walter Thiele, Christina Marie Maulide, Nuno
Copyright Year	2015
Abstract	Contemporary catalytic procedures involving alkylpalladium(ii) have enriched the arsenal of synthetic organic chemistry. Those transformations usually rely on internal coordination through "directing groups", carefully designed to maximize catalytic efficiency and regioselectivity. Herein, we report structural and reactivity studies of a series of internally coordinated monohaptoallylpalladium complexes. These species enable the direct spectroscopic observation and theoretical study of π-σ-π interconversion processes. They further display unusual dynamic behavior which should be of direct relevance to chemistries beyond catalytic allylic alkylation.
Starting Page	5734
Ending Page	5739
Page Count	6
File Format	PDF HTM / HTML
PubMed reference number	29910865v1
Alternate Webpage(s)	https://doi.org/10.1039/c5sc01867f
DOI	10.1039/c5sc01867f
Journal	Chemical science
Volume Number	6
Language	English
Access Restriction	Open
Subject Keyword	Alkylation Chemistry, Organic Electronic Supplementary Materials cell transformation
Content Type	Text
Resource Type	Article