Synthesis and crystal structure of Cu3(Bipy)2(L1)2(L2)2⋅ 4H2O(Bipy = 2,2′-bipyridine, L1 =1-((2-sulfonateethylimino)methyl)-2-naphthol), L2 = 2-hydroxy-1-naphthaldehyde)

Content Provider	Semantic Scholar
Author	Wang, Xiu-Jian Jiang, Yi-Min Wang, Jun-Bo Zhong, Xin-Xian
Copyright Year	2005
Abstract	The title compound, Cu3(Bipy)2(L1)2(L2)2⋅4H2O, was synthesized in the methanol solution of Bipy and Cu(II) in the presence of 1-((2-sulfonate-ethylimino)-methyl)-2-naphthol (L1), which was condensation compound of taurine and 2-hydroxy-1-naphthaldehyde. This complex crystallized in the space group P-1 with a = 9.825(2) Å, b = 12.626(2) Å, c = 14.342(3) Å, α = 90.29(1)∘, β = 100.67(1)∘, γ = 101.67(2)∘, and Z = 2. In the trinuclear Cu(II) complex, there are two type Cu atoms which have square and square pyramid geometries, respectively. The Cu–N distances vary from 1.965(3) to 2.000(4) Å, while the Cu–O distances are between 1.896(3) and 2.337(4) Å.
Starting Page	885
Ending Page	889
Page Count	5
File Format	PDF HTM / HTML
DOI	10.1007/s10870-005-5133-9
Volume Number	35
Alternate Webpage(s)	https://page-one.springer.com/pdf/preview/10.1007/s10870-005-5133-9
Alternate Webpage(s)	https://doi.org/10.1007/s10870-005-5133-9
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article