NDLI: Nanoscale cobalt metal–organic framework as a catalyst for visible light-driven and electrocatalytic water oxidation

Content Provider	Semantic Scholar
Author	Xu, Qian Chi, Lê Thị Loan Wang, Jide
Copyright Year	2016
Abstract	The Co-ZIF-67 metal–organic framework was investigated as a catalyst for visible light-driven and electrocatalytic water oxidation in basic and neutral media. Co-ZIF-67 exhibited efficient performance for visible light-driven water oxidation, with a turnover frequency of 0.035 s−1. Co-ZIF-67 also maintained a stable current density after electrolysis for over 24 h, and it electrocatalyzed the oxygen evolution reaction within a wide pH range. DFT calculations suggest that the catalyst activates water molecules while the dissociated proton is received by nearby 2-methylimidazole ligands. This process permits Co-ZIF-67 to effectively catalyze the photocatalytic and electrocatalytic oxidation of water.
Starting Page	3032
Ending Page	3035
Page Count	4
File Format	PDF HTM / HTML
DOI	10.1039/C5NJ03113C
Volume Number	40
Alternate Webpage(s)	https://pubs.rsc.org/en/content/getauthorversionpdf/C5NJ03113C
Alternate Webpage(s)	https://doi.org/10.1039/C5NJ03113C
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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