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Development of novel synthetic routes to bis(perfluoroalkyl)-substituted anthracene derivatives
| Content Provider | Semantic Scholar |
|---|---|
| Author | Yamada, Shigeyuki Kinoshita, Keita Iwama, Shota Yamazaki, Takashi Kubota, Toshio Yajima, Tomoko |
| Copyright Year | 2013 |
| Abstract | Commercially available anthraquinones were smoothly converted to either symmetrically or unsymmetrically substituted 9,10-bis(perfluoroalkyl)anthracene-9,10-diols by way of bistrifluoromethylation or successive trifluoromethylation-nucleophilic perfluoroalkylation, respectively, and these diols can be easily aromatized to form bis(perfluoroalkyl)anthracene derivatives in good yields by treatment with a mixture of CBr4 and PPh3. Further cross-coupling reactions using halogen-containing anthracene derivatives realized a successful extension of the original π-conjugation systems. |
| Starting Page | 6803 |
| Ending Page | 6806 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| Volume Number | 3 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/ra/c3/c3ra40974k/c3ra40974k.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C3RA40974K |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
