NDLI: Ligand mixed-valence and electrical conductivity in coordination complexes containing a redox-active phenalenol-substituted ligand.

Content Provider	Semantic Scholar
Author	Dale, Sarah Bonanno, Nico M. Pelaccia, Mark Lough, Alan J. Miyawaki, Atsuhiro Takahashi, Kazuyuki Lemaire, Martin T.
Copyright Year	2019
Abstract	A new redox-active hydrazone ligand bearing a phenalenol group is described (phpl), which produces neutral six-coordinate Fe and Co complexes (1 & 2) with the ligands identified in different oxidation states; an open-shell anion radical and closed-shell dianion. An intense and very low-energy intervalence charge transfer (IVCT) band is identified in solid-state and in solution in the complexes. Single crystals of 1 are semiconducting (at 300 K, σ = 3.05 × 10-4 S cm-1 with Ea = 245 meV).
Starting Page	8053
Ending Page	8056
Page Count	4
File Format	PDF HTM / HTML
DOI	10.1039/c9dt01788g
Alternate Webpage(s)	http://www.rsc.org/suppdata/c9/dt/c9dt01788g/c9dt01788g1.pdf
PubMed reference number	31116216
Alternate Webpage(s)	https://doi.org/10.1039/c9dt01788g
Journal	Medline
Volume Number	48
Issue Number	23
Journal	Dalton transactions
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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