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Influence of Cu2O Addition on Crystallization Process and Microstructure of Transparent Mica Glass-Ceramics
| Content Provider | Semantic Scholar |
|---|---|
| Author | Taruta, Seiichi Sakai, Keigo Yamakami, Tomohiko Yamaguchi, Tomohiro |
| Copyright Year | 2014 |
| Abstract | The influence of Cu2O addition on crystallization process and microstructure of the transparent mica glass-ceramics was investigated. Cu+ ions which were added as Cu2O were oxidized to Cu2+ ions during preparation of parent glasses and the Cu2+ ions were reduced to Cu+ ions again during heating of the parent glasses. By heating the parent glasses to which 10-20 mol% Cu2O was added at 650-700°C, not only nanosized micas but also Cu2O nanoparticles separeted. Their separation temperatures were lowered as the additive amount of Cu2O increased. Micas separated at 750°C should contain Cu+ and Cu2+ ions in the structure. Metallic Cu was observed only in the specimen to which 1 mol% Cu2O was added. |
| Starting Page | 209 |
| Ending Page | 212 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.4028/www.scientific.net/kem.617.209 |
| Volume Number | 617 |
| Alternate Webpage(s) | https://soar-ir.repo.nii.ac.jp/?action=repository_action_common_download&item_id=18365&item_no=1&attribute_id=65&file_no=1 |
| Alternate Webpage(s) | https://doi.org/10.4028/www.scientific.net%2Fkem.617.209 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |