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2-Vinylpyridine–tris(pentafluorophenyl)borane hexane monosolvate
| Content Provider | Semantic Scholar |
|---|---|
| Author | Klahn, Marcus Spannenberg, Anke Rosenthal, Uwe |
| Copyright Year | 2012 |
| Abstract | The title compound, C(7)H(7)N·B(C(6)F(5))(3)·C(6)H(14), was obtained by the stoichiometric reaction of 2-vinyl-pyridine and tris-(penta-fluoro-phen-yl)borane in toluene. The formed adduct exhibits a restricted rotation along the B-N bond resulting in an asymmetry, which can be also observed in the (19)F NMR spectra. The B-N distance is equivalent to the distances found for 2-methyl-pyridine and 2-ethyl-pyridine B(C(6)F(5))(3) adducts. For the final refinement, the contributions of disordered solvent mol-ecules were removed from the diffraction data with SQUEEZE in PLATON [van der Sluis & Spek (1990). Acta Cryst. A46, 194-201; Spek (2009). Acta Cryst. D65, 148-155]. |
| Starting Page | o1261 |
| Ending Page | o1261 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S1600536812013153 |
| PubMed reference number | 22606190 |
| Journal | Medline |
| Volume Number | 68 |
| Alternate Webpage(s) | http://journals.iucr.org/e/issues/2012/04/00/vm2164/vm2164.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536812013153 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |