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Conjugate Addition of Organozinc Compounds to Nitroolefins Conjugate Addition of Organozinc Compounds to Nitroolefins
| Content Provider | Semantic Scholar |
|---|---|
| Author | Rimkus, Audrius Sewald, Norbert |
| Copyright Year | 2003 |
| Abstract | SYNTHESIS 2004, No. 1, pp 0135–0146xx.xx.2003 Advanced online publication: 25.11.2003 DOI: 10.1055/s-2003-44355; Art ID: Z14103SS © Georg Thieme Verlag Stuttgart · New York Abstract: Symmetrical (R2Zn) or mixed diorganozinc compounds (R1ZnR2) smoothly react with a series of nitroolefins in the presence of catalytic amounts of copper(I) salts and provide synthetically versatile nitro compounds in moderate to good yields. Simple alkyl groups, functionalized residues, or mixed trimethylsilylmethyl organozinc compounds (TMSM)ZnR may be employed for conjugate addition, while the TMSM group is not being transferred. ipso-Substitution is observed in absence of the copper(I) salt. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://www.xiuzhengrd.com/ejournals/pdf/synthesis/doi/10.1055/s-2003-44355.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |