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Structural Study and Solution Integrity of Dioxomolybdenum(VI) Complexes with Tridentate Schiff Base and Azole Ligands
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zhang, Cungen Rheinwald, Gerd Lozan, Vasile Wu, Biao Lassahn, Paul-Gerhard Lang, Heinrich Janiak, Christoph |
| Copyright Year | 2002 |
| Abstract | Four new molybdenum complexes (Mo VI O2(L 1 )(Him)) (1), (Mo VI O2(L 1 )(3-MepzH) (2), (Mo VI O2(L 2 )(3-MepzH)) (3), and ((Mo VI O2)2(ยต-L 3 )(MeOH)2 )( 4) were synthesized and characterized by IR, NMR, ESI-MS, and single-crystal structure analysis (H2L 1 2-(salicylideneamino)-2-methyl-1-propanol, H2L 2 2-(3- methoxysalicylideneamino)-2-methyl-1-propanol, H4L 3 1,7- bis(salicylidene)dihydrazide malonic acid, Him imidazole and 3- MepzH 3-methylpyrazole). In all four structures the molyb- denum atom has a distorted octahedral coordination with the three meridional donor atoms from the Schiff base di- or tetraanion (L 1,2 ) 2 /(L 3 ) 4 and one oxo group occupying the sites of the equa- torial plane. The other oxo group and the azole or methanol mol- ecule occupy the apical sites. In 1-3 two centrosymmetrically related |
| Starting Page | 1259 |
| Ending Page | 1268 |
| Page Count | 10 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://portal.uni-freiburg.de/janiak/veroffentlichungen/pdf/pdf119 |
| Alternate Webpage(s) | https://doi.org/10.1002/1521-3749%28200206%29628%3A6%3C1259%3A%3AAID-ZAAC1259%3E3.0.CO%3B2-Q |
| Volume Number | 628 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
