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Alkylation of Benzene with 1-Alkenes over Zeolite Y and Mordenite
| Content Provider | Semantic Scholar |
|---|---|
| Author | Horňáček, Michal Hudec, Pavol Smiešková, Agáta Jakubík, Tibor |
| Copyright Year | 2009 |
| Abstract | Influence of reaction temperature, molar ratio of benzene to 1-alkenes, weight of catalyst and length of hydrocarbon chain of 1-alkenes were tested in alkylation of benzene by 1-alkenes. The liquid-phase alkylation was carried out in autoclave at autogeneous pressure. Synthetic zeolites of Y-type and mordenite in H-forms were tested as solid catalysts. Zeolites were characterized by XRD, N2 adsorption, FTIR with pyridine adsorption and NH3-TPD. The influence of the reaction conditions (temperature, molar ratio benzene to 1-alkenes and weight of catalyst) on the conversion and selectivity to 2-phenyl isomer was studied with different 1alkenes from C6 to C18. The activity of Y-zeolite was greater then that of mordenite but the selectivity to 2-phenyl isomer was much better in the case of mordenite catalyst. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://fez.schk.sk/eserv/changeme:4995/acs_0034.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |