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Bis{(E)-3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamido(2−)]bis{[(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamide]copper(II)} bis((E)-{3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropyl}carbamate) aceton
| Content Provider | Semantic Scholar |
|---|---|
| Author | Buvailo, Andrii I. Pavlishchuk, Anna Penkova, Larysa V. Kotova, Natalia V. Haukka, Matti |
| Copyright Year | 2012 |
| Abstract | The reaction between copper(II) nitrate and (E)-N-(3-amino-2,2-dimethyl-prop-yl)-2-(hy-droxy-imino)-propanamide led to the formation of the dinuclear centrosymmetric copper(II) title complex, (C8H18N3O2)2[Cu2(C8H15N3O2)2(C8H17N3O2)2](C9H16N3O4)2·2CH3CN, in which an inversion center is located at the midpoint of the Cu2 unit in the center of the neutral [Cu2(C8H15N3O2)2(C8H17N3O2)2] complex fragment. The Cu(2+) ions are connected by two N-O bridging groups [Cu⋯Cu separation = 4.0608 (5) Å] while the Cu(II) ions are five-coordinated in a square-pyramidal N4O coordination environment. The complex mol-ecule co-crystallizes with two mol-ecules of acetonitrile, two mol-ecules of the protonated ligand (E)-3-[2-(hy-droxy-imino)-propanamido]-2,2-dimethyl-propan-1-aminium and two negatively charged (E)-{3-[2-(hy-droxy-imino)-propanamido]-2,2-dimethyl-prop-yl}carbamate anions, which were probably formed as a result of condensation between (E)-N-(3-amino-2,2-dimethyl-prop-yl)-2-(hy-droxy-imino)-propanamide and hydro-gencarbonate anions. In the crystal, the complex fragment [Cu2(C8H15N3O2)2(C8H17N3O2)2] and the ion pair C8H18N3O2(+.)C9H16N3O4(-) are connected via an extended system of hydrogen bonds. |
| Starting Page | m1480 |
| Ending Page | m1481 |
| Page Count | 2 |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S160053681204620X |
| Alternate Webpage(s) | http://journals.iucr.org/e/issues/2012/12/00/gg2096/gg2096.pdf |
| PubMed reference number | 23468704 |
| Alternate Webpage(s) | https://doi.org/10.1107/S160053681204620X |
| Journal | Medline |
| Volume Number | 68 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
