NDLI: Determination of nitrated and oxygenated polycyclic aromatic hydrocarbons in water samples by a liquid–liquid phase microextraction procedure based on the solidification of a floating organic drop followed by solvent assisted back-extraction and liquid chromatography–tandem mass spectrometry

Please wait, while we are loading the content...

Determination of nitrated and oxygenated polycyclic aromatic hydrocarbons in water samples by a liquid–liquid phase microextraction procedure based on the solidification of a floating organic drop followed by solvent assisted back-extraction and liquid chromatography–tandem mass spectrometry

Content Provider	Semantic Scholar
Author	Guiñez, María Bazán, Cristian Martínez, Luis Cerutti, Soledad
Copyright Year	2018
Abstract	Abstract A methodology was optimized for the determination of nitrated-PAHs (nitro-PAHs) and oxygenated-PAHs (oxy-PAHs) in natural waters. The extraction/preconcentration procedure was performed by liquid–liquid phase microextraction based on the solidification of a floating organic drop followed by a novel solvent assisted back-extraction (DLLME-SFO-SBE) combined with liquid chromatography-tandem mass spectrometry. The solvent assisted back extraction into a suitable solvent enabled the direct injection of nitro and oxy-PAHs into the UHPLC-(+)APCI-MS/MS system. Parameters affecting the efficiency of the back-extraction procedure were evaluated and optimized, including the nature of the back-extractant volume, temperature and agitation effect. Additionally, various strategies related to the emulsion formation process were assayed. Detection and quantification limits were in the range of 0.02–0.85 ng mL−1 and 0.15–1.10 ng mL−1. Acceptable extraction recoveries between 95.1 and 100% and enrichment factors between 192 and 200-fold, with relative standard deviations
Starting Page	164
Ending Page	173
Page Count	10
File Format	PDF HTM / HTML
DOI	10.1016/j.microc.2018.02.027
Alternate Webpage(s)	https://ri.conicet.gov.ar/bitstream/handle/11336/87353/CONICET_Digital_Nro.e293a414-c0c2-4551-902f-ba146144284e_D.pdf?isAllowed=y&sequence=5
Alternate Webpage(s)	https://doi.org/10.1016/j.microc.2018.02.027
Volume Number	139
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

Central Library (ISO-9001:2015 Certified)
Indian Institute of Technology Kharagpur
Kharagpur, West Bengal, India | PIN - 721302

See location in the Map
03222 282435
Mail: support@ndl.gov.in

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in