NDLI: A macrocyclic oligofuran: synthesis, solid state structure and electronic properties† †Electronic supplementary information (ESI) available. CCDC 1892379. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc03247a

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A macrocyclic oligofuran: synthesis, solid state structure and electronic properties† †Electronic supplementary information (ESI) available. CCDC 1892379. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc03247a

Content Provider	Semantic Scholar
Author	Mulay, Sandip V. Dishi, Or Fang, Yuan Niazi, Muhammad R. Shimon, Linda J. W. Perepichka, Dmitrii F. Gidron, Ori
Copyright Year	2019
Abstract	We report the first π-conjugated macrocyclic system with an oligofuran backbone. The calculated HOMO-LUMO gap is similar to that of the corresponding linear polymer, indicating a remarkable electron delocalization. The X-ray structure reveals a planar conformation, in contrast to the twisted conformation of macrocyclic oligothiophenes. The intermolecular π-π stacking distance is extremely small (3.17 Å), indicating very strong interactions. The macrocycle forms large π-aggregates in solution and shows a tendency toward highly ordered multilayer adsorption at the solid-liquid interface. The face-on orientation of molecules explains the higher hole mobility observed in the out-of-plane direction.
Starting Page	8527
Ending Page	8532
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1039/C9SC03247A
PubMed reference number	32055302
Journal	Medline
Volume Number	10
Alternate Webpage(s)	https://pubs.rsc.org/en/content/articlepdf/2019/sc/c9sc03247a
Alternate Webpage(s)	https://doi.org/10.1039/C9SC03247A
Journal	Chemical science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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