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Tris(1,10-phenanthroline-κ2 N,N′)nickel(II) bis(hexafluoridophosphate)
| Content Provider | Semantic Scholar |
|---|---|
| Author | Hamdani, Hicham El Amane, Mohamed El Duhayon, Carine |
| Copyright Year | 2018 |
| Abstract | The asymmetric unit of the title compound, [Ni(C36H24N6)3](PF6)2, contains one and a half nickel(II) complex dications and three hexafluoridophosphate anions, one of the dications having crystallographic twofold rotational symmetry. Each NiII atom displays a distorted octahedral coordination geometry provided by the six N atoms of three bidentate 1,10-phenanthroline ligands with bite angles of 79.68 (11)–80.76 (12)°. In the crystal, C—H⋯F hydrogen bonds link the anions and dications into a three-dimensional supramolecular framework. Within the framework complex dications with twofold rotational symmetry are linked by weak π–π stacking interactions [centroid-to-centroid distances = 3.712 (2) A]. |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/s2414314618007095 |
| Volume Number | 3 |
| Alternate Webpage(s) | http://iucrdata.iucr.org/x/issues/2018/05/00/rz5231/rz5231.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/s2414314618007095 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
