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Hydrothermal synthesis of a new zinc phosphite (C5H7N2)2·[Zn3(HPO3)4] with intersecting 8- and 12-ring channels
| Content Provider | Semantic Scholar |
|---|---|
| Author | Dong, Zhaojun Zhang, Wenqing Wang, Yu Li, Jiyang |
| Copyright Year | 2015 |
| Abstract | Using 4-aminopyridine as the structure-directing agent(SDA), a new open-framework zinc phosphite, (C5H7N2)2·[Zn3(HPO3)4](ZnHPO-CJ70), was synthesized under hydrothermal condition. Single-crystal X-ray diffraction analysis reveals that ZnHPO-CJ70 is constructed by the strictly alternating ZnO4 tetrahedra and HPO3 pseudo-pyramids, with their vertexes linked to generate a three-dimensional(3D) open framework with intersecting 8- and 12-ring channels. Further characterizations of ZnHPO-CJ70 were performed by means of X-ray powder diffraction(XRD), elemental analysis(ICP, CHN), infrared spectroscopy(IR) and thermogravimetric(TG) analyses. The results of luminescent test shows that ZnHPO-CJ70 exhibits strong fluorescence emissions in the solid state at room temperature. |
| Starting Page | 498 |
| Ending Page | 502 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| DOI | 10.1007/s40242-015-5021-6 |
| Volume Number | 31 |
| Alternate Webpage(s) | https://page-one.springer.com/pdf/preview/10.1007/s40242-015-5021-6 |
| Alternate Webpage(s) | https://doi.org/10.1007/s40242-015-5021-6 |
| Journal | Chemical Research in Chinese Universities |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |