NDLI: Copolymers of 2-hydroxyethylacrylate and 2-methoxyethyl acrylate by nitroxide mediated polymerization: kinetics, SEC-ESI-MS analysis and thermoresponsive properties

Content Provider	Semantic Scholar
Author	Hoogenboom, Richard Zorn, Anna-Marie Keul, Helmut Barner-Kowollik, Christopher Moeller, Martin
Copyright Year	2012
Abstract	The nitroxide mediated copolymerization of 2-hydroxyethyl acrylate (HEA) and 2-methoxyethyl acrylate (MEA) is reported. The copolymerization kinetics followed the persistent radical model and revealed the formation of well-defined ideal random copolymers (rHEA = 0.93 ± 0.09; rMEA = 0.95 ± 0.09). SEC-ESI-MS proved the presence of both the initiation fragment and SG1 as chain ends of the polymers. The cloud point temperature of the copolymers increased from 5 °C and 60 °C with increasing HEA content from 0% to 70% and they are discussed in relation to both monomer and end-group structure.
Starting Page	335
Ending Page	342
Page Count	8
File Format	PDF HTM / HTML
DOI	10.1039/C1PY00344E
Volume Number	3
Alternate Webpage(s)	http://www.rsc.org/suppdata/py/c1/c1py00344e/c1py00344e.pdf
Alternate Webpage(s)	https://doi.org/10.1039/C1PY00344E
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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